Facile Self-Assembly of Supramolecular Hexakisferrocenyl Triangles via Coordination-Driven Self-Assembly and Their Electrochemical Behavior

A novel family of hexakis(ferrocenyl) triangles has been successfully constructed from newly designed 60° ferrocenyl building blocks via coordination-driven self-assembly. The structures of all triangles were characterized by multinuclear NMR (1H and 31P), ESI-TOF-MS, and elemental analysis, and their electrochemical behavior has been investigated.

本研究通过全新设计的60°二茂铁基构筑单元，经配位驱动自组装（coordination-driven self-assembly）策略，成功构建了一类新型六(二茂铁基)三角形化合物家族。所有该类三角形化合物的结构均通过多核核磁共振波谱（multinuclear NMR，涵盖1H与31P谱）、电喷雾电离飞行时间质谱（ESI-TOF-MS）以及元素分析完成表征，并对其电化学行为展开了研究。