Palladium-Catalyzed Double Alkylation of 3‑Aryl-2-fluoroallyl Esters with Malonate Nucleophiles through the Carbon–Fluorine Bond Cleavage
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https://figshare.com/articles/dataset/Palladium_Catalyzed_Double_Alkylation_of_3_Aryl_2_fluoroallyl_Esters_with_Malonate_Nucleophiles_through_the_Carbon_Fluorine_Bond_Cleavage/2325538
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The alkylation of (Z)-3-aryl-2-fluoroallyl acetate with the malonate anion by the [Pd(C3H5)(cod)]BF4/2,2′-bpy catalyst proceeds through the carbon–fluorine bond cleavage, and 2 equiv of the malonate nucleophile was introduced to the allyl substrate.
创建时间：
2016-02-18
