Crystallization-Driven Multicomponent Encapsulation of Coulombically Repulsive Guests
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https://figshare.com/articles/dataset/Crystallization_Driven_Multicomponent_Encapsulation_of_Coulombically_Repulsive_Guests/2154202
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资源简介：
Coulombically
repulsive cationic guests can be encapsulated in
the multicomponent capsule hosts via favorable ion pairing, H-bonding
intermolecular interactions. The inclusion of protonated and diprotonated
2-pycolyl amine guests in the calix[4]arene tetrasulfonate, tetrasodium
salt C[4]) host is reminiscent with complex dynamic equilibria
in solution. The addition of AG aminoguanidinium cations
to such mixtures results in the formation of distinct crystalline
bilayer and capsule architectures in the solid state. This show that
libraries of interexchanging supramolecular components may convert
into robust solid state multicomponent capsules via constitutional
crystallization.
创建时间：
2016-02-13
