Regio- and Stereoselective Multisubstituted Enol Ester Synthesis
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https://figshare.com/articles/dataset/Regio_and_Stereoselective_Multisubstituted_Enol_Ester_Synthesis/2589448
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资源简介:
Regio- and stereoselective cohalogenation of alkynes
with NXS (X
= Br, I) was achieved, and the stereoselectivity of the resulting
alkenes was dependent on the substituent on the alkyne. Cohalogenation
and successive cross-coupling gave multisubstituted enol esters in
a one-pot process.
本研究成功实现了炔烃与N-卤代琥珀酰亚胺(NXS,X=Br、I)的区域选择性及立体选择性共卤化反应;所得烯烃的立体选择性由炔烃上的取代基决定。通过一锅法依次开展共卤化与交叉偶联反应,即可得到多取代烯醇酯类产物。
创建时间:
2011-11-04



