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A Crown-Shaped 24-Molybdate Cluster Constructed by Organotriphosphonate Ligand

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Crown_Shaped_24_Molybdate_Cluster_Constructed_by_Organotriphosphonate_Ligand/2390725
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A crown-shaped organic–inorganic hybrid polyoxomolybdate, Na5[H7{N­(CH2PO3)3}­Mo6O16(OH) (H2O)4]4·18H2O (1) has been presented and characterized. Such an intriguing structure consists of a 24-molybdenum-membered polyanion constructed by organotriphosphonate ligands, which represents the highest nuclearity of metal atoms in the area of organophosphonate-based polyoxometalates.
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2016-02-19
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