PhI(OCOCF3)2‑Mediated C–C Bond Formation Concomitant with a 1,2-Aryl Shift in a Metal-Free Synthesis of 3‑Arylquinolin-2-ones
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/PhI_OCOCF_sub_3_sub_sub_2_sub_Mediated_C_C_Bond_Formation_Concomitant_with_a_1_2_Aryl_Shift_in_a_Metal_Free_Synthesis_of_3_Arylquinolin_2_ones/2403286
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The reaction of the readily available N-methyl-N-phenylcinnamamides with phenyliodine bis(trifluoroacetate) (PIFA) in the presence of Lewis acids provides a general and efficient assembly of a variety of 3-arylquinolin-2-one compounds. This novel approach features not only metal-free oxidative C(sp2)–C(sp2) bond formation but also an exclusive 1,2-aryl migration.
创建时间：
2016-02-19
