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Water-mediated inclusion of benzoates and tosylates inside the bambusuril macrocycle

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DataCite Commons2026-03-24 更新2025-04-16 收录
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A supramolecular complex between benzoates and a bambusuril crystallizes out immediately after mixing in chloroform but only in the presence of residual water molecules. In this complex each of the two portals of the macrocycle is occupied by one benzoate. Carboxylate groups are connected through hydrogen bo

苯甲酸根(benzoate)与竹脲大环(bambusuril)形成的超分子复合物(supramolecular complex),在氯仿(chloroform)中混合后会立即析出结晶,但该过程仅在残留水分子存在的条件下才可发生。在该复合物中,此大环化合物的两个端口各自结合一个苯甲酸根。羧酸根基团通过氢
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SupraBank
创建时间:
2021-09-28
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