B(C6F5)3-Catalysed Chemo- and Regioselective C–H Chalcogenation of Arenes and Heteroarenes: data

The synthesis of chalcogenides remains a subject of valuable research due to their widespread biological applications, particularly in pharmaceuticals. Selective aromatic Csp2–H functionalisation is a promising tool for synthesising diaryl chalcogenides. Herein, our study details the tris(pentafluorophenyl)borane [B(C6F5)3]-catalysed Csp2–H functionalisation of a wide range of readily available arenes, heteroarenes, and pharmacophores with thiosuccinimides or selenosuccinimides, providing access to a broad range of highly chemo- and regioselective chalcogenated products. The data includes a collection of files for the synthesis and characterisation of the compounds reported in this work.

硫族化合物（chalcogenides）的合成始终是颇具研究价值的课题，因其拥有广泛的生物应用场景，尤其在制药领域应用突出。选择性芳香族Csp²-H官能化反应是合成二芳基硫族化合物的极具潜力的手段。本研究详细阐述了以三(五氟苯基)硼烷[B(C₆F₅)₃]为催化剂，以硫代琥珀酰亚胺或硒代琥珀酰亚胺为试剂，对多种易得的芳烃、杂芳烃以及药效团进行Csp²-H官能化的方法，由此可获得一系列具有高度化学选择性与区域选择性的硫族化产物。本数据集包含本研究中所报道化合物的合成与表征相关文件集。