1,1-Diboration of Isocyanides with [2]Borametalloarenophanes

A series of new [3]diboracarbametalloarenophanes was synthesized by reaction of [2]borametalloarenophanes or [3]diboraplatinametalloarenophanes with isocyanides and was fully characterized by multinuclear NMR spectroscopy and, in the case of [Fe{η5-C5H4B(NMe2)}2CN-t-Bu], additionally by X-ray diffraction analysis.

一系列新型[3]二硼碳金属芳环藩合物([3]diboracarbametalloarenophanes)通过[2]硼金属芳环藩合物([2]borametalloarenophanes)或[3]二硼铂金属芳环藩合物([3]diboraplatinametalloarenophanes)与异氰类化合物(isocyanides)的反应合成，并经多核核磁共振波谱法(multinuclear NMR spectroscopy)完成全面表征；对于配合物[Fe{η⁵-C₅H₄B(NMe₂)}₂C=N-t-Bu]，还额外通过X射线衍射分析(X-ray diffraction analysis)进行了表征。