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Reversible Addition of Alkynes to Gallium Complex of Chelating Diamide Ligand

NIAID Data Ecosystem2026-03-06 收录

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https://figshare.com/articles/dataset/Reversible_Addition_of_Alkynes_to_Gallium_Complex_of_Chelating_Diamide_Ligand/2760424 数据链接链接失效反馈

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Reversible Addition of Alkynes to Gallium Complex of Chelating Diamide Ligand

螯合二酰胺配体镓配合物与炔烃的可逆加成反应

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创建时间：

2016-02-24

金属簇合物合成

有机金属化学

The reaction of [{Cp(CO)2Fe}BiCl2] (1a) with [Co(CO)4]- leads to the formation of the first heteroleptic substituted bismuthane, [(μ3-Bi){Co(CO)4}2{Fe(CO)2Cp}] (2). When the “open” complex 2 is irradi

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Seven-Membered Cyclic Dialkylstannylene and -Plumbylene Compounds Stabilized by Agostic-type B−H···E Interactions [E = Sn, Pb]

有机金属化学

化合物稳定性

The reaction between [[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]Li(THF)3]2 and either Cp2Sn or Cp2Pb in toluene cleanly gives the compounds rac-[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]2E in moderate yield [E = Sn

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Reactivity of the Unsaturated Triosmium Cluster Os 3 (CO) 8 (μ 3 -η 2 -Ph 2 PCH 2 P(Ph)C 6 H 4 )(μ-H) with Benzothiophene: Activation of a P−C Bond in Diphosphine and a C−H Bond in Benzothiophene

有机金属化学

键活化机理

Treatment of the electronically unsaturated cluster Os3(CO)8(μ3-η2-Ph2PCH2P(Ph)C6H4)(μ-H) (1) with benzothiophene in refluxing m-xylene afforded Os3(CO)7(μ-PPh2)(μ-PMePh)(μ3-η2-C6H4) (2), Os3(CO)7(μ3-

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CCDC 252699: Experimental Crystal Structure Determination

晶体结构分析

有机金属化学

Related Article: I.R.Crossley, A.F.Hill, A.C.Willis|2005|Organometallics|24|1062|doi:10.1021/om040128f

Mendeley Data2024-06-25 更新80

Adding a New Dimension to the Investigation of Platinum-Mediated Arene C−H Activation Reactions Using 2D NMR Exchange Spectroscopy. Dynamics of Pt(II) Phenyl/Benzene Site Exchange

有机金属化学

配体交换动力学

Protonation of (N−N)PtPh2 (1; N−N = diimine ArNCMe−CMeNAr with Ar = 2,6-Me2C6H3 (a), 2,4,6-Me3C6H2 (b), 4-Br-2,6-Me2C6H2 (c), 3,5-Me2C6H3 (d), and 4-CF3C6H4 (e)) in the presence of MeCN at ambient t

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Reversible Addition of Alkynes to Gallium Complex of Chelating Diamide Ligand

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