Data underlying the publication: "Redox-Controlled Shunts in a Synthetic Chemical Reaction Cycle"

Complete set of data underlying the experiments conducted in "Redox-Controlled Shunts in a Synthetic Chemical Reaction Cycle". The aim of this publication is to demonstrate a new use of beta'-substituted Michael acceptors (MAs). A new Chemical Reaction Network (CRN) is based based on addition-elimination- as well as oxidation-chemistry. An amine-functionalised MA can be turned into a thiol-functionalised MA with a thiol. This deactivated MA can be reactivated with different oxidants, making it prone to amine-readdition, recovering the starting material. We show that different oxidants lead to different pathways of this CRN with different side products and kinetics. Further, we show a flow-controlled switching between different species of this CRN, offering the ability to recover the starting material and recycle the waste species (disulfide).Please refer to the readme file, explaining the experiment identifiers and conditions of each experiment.

本数据集为《合成化学反应循环中的氧化还原控制分流》一文所开展实验的完整底层数据。该研究旨在展示β'-取代迈克尔受体（Michael acceptors, MAs）的全新应用方向。本工作构建了一种基于加成-消除与氧化反应机制的新型化学反应网络（Chemical Reaction Network, CRN）：可通过巯基将胺官能化的迈克尔受体转化为巯基官能化的迈克尔受体；该失活的迈克尔受体可通过不同氧化剂实现再活化，使其易于发生胺类再加成反应，从而回收起始原料。研究表明，不同氧化剂会使该化学反应网络呈现出不同的反应路径，并伴随不同的副产物与反应动力学特征。此外，本研究还实现了该化学反应网络不同物种间的流控式切换，可实现起始原料的回收与副产物二硫化物的循环利用。请参阅说明文件，其中阐释了各实验的实验标识符与实验条件。