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Exo-Selective and Enantioselective Photoenolization/Diels–Alder Reaction

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Figshare2021-09-22 更新2026-04-28 收录
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https://figshare.com/articles/dataset/_i_Exo_i_-Selective_and_Enantioselective_Photoenolization_Diels_Alder_Reaction/16661387
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An unusual exo-selective photoenolization/Diels–Alder reaction of electron-rich 2-methylbenzaldehydes and dienophiles containing a benzoyl group at its α position was reported herein. The chiral TADDOL-type ligand plays a key role in this process: (1) accelerating the reaction; (2) controlling the enantioselectivity; and (3) improving and tuning the diastereoselectivity of the reaction.
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2021-09-22
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