Materials Data on NClO3 by Materials Project

ClONO2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two chlorine nitrate molecules. N is bonded in a trigonal planar geometry to three O atoms. There is two shorter (1.20 Å) and one longer (1.64 Å) N–O bond length. There are two inequivalent O sites. In the first O site, O is bonded in a water-like geometry to one N and one Cl atom. The O–Cl bond length is 1.67 Å. In the second O site, O is bonded in a single-bond geometry to one N atom. Cl is bonded in a single-bond geometry to one O atom.硝酸氯（ClONO₂）结晶于单斜晶系Cm空间群。该结构为零维结构，包含两个硝酸氯分子。氮原子以平面三角形配位构型与三个氧原子成键，存在两条键长为1.20 Å的较短N–O键与一条键长为1.64 Å的较长N–O键。体系中存在两个不等价的氧位点：在第一个氧位点中，氧原子以类水配位环境分别与一个氮原子和一个氯原子成键，O–Cl键键长为1.67 Å；在第二个氧位点中，氧原子以单键配位环境仅与一个氮原子成键。氯原子以单键配位环境与一个氧原子成键。