Al-Ni-Co quasicrystalline melt-spun alloy - microstructure and catalytic properties

This set contains supplementary data for the work: Al-Ni-Co decagonal quasicrystal application as an energy-effective catalystfor phenylacetylene hydrogenation, Sustainable Materials and Technologies 41 (2024) e01055, https://doi.org/10.1016/j.susmat.2024.e01055

SEM BSE images present the microstructure of the cross-section of the ribbon.

MS_Surf images show the surface of the ribbons acquired using an optical microscope.

TEM images were named as follows:

ms_ribb - melt-spun ribbon

nabh4_ribb - ribbon cleaned with NaBH4 aqueous solution

liq_ribb - ribbon recovered after phenylacetylene hydrogenation reaction 

phenylacetylene hydrogenation reactions.ods - Reaction course of phenylacetylene hydrogenation reactions with new portions of catalyst. Chemical composition of the reaction mixture was evaluated using the gas chromatography method.

XPS spectra were collected for surfaces of ribbons in a melt-spun form and recovered after the phenylacetylene hydrogenation reaction. 

The material preparation and microstructural analyses were performed at the Institute of Metallurgy and Materials Science of the Polish Academy of Sciences.

The experimental procedure for material preparation, instrumentation, data collection and results analysis were described in the work: https://doi.org/10.1016/j.susmat.2024.e01055

Preparation of materials: Amelia Zięba

TEM images collection (FEI Tecnai G2, ThermoFisher Titan Themis G2 200 Probe Cs-Corrected): Amelia Zięba, Lidia Lityńska-Dobrzyńska

SEM images acquisition (FEI E-SEM XL-30): Amelia Zięba

Catalytic performance tests: Dorota Duraczyńska

XPS study: Mateusz Marzec

Acknowledgements

The work was financially supported by the National Science Centre (NCN), Poland, project No. 2021/41/N/ST8/02533.

本数据集为下述研究工作的补充数据：《Al-Ni-Co十次准晶作为苯乙炔加氢高效节能催化剂的应用》，刊载于Sustainable Materials and Technologies 41 (2024) e01055，DOI：10.1016/j.susmat.2024.e01055

扫描电子显微镜背散射电子（SEM BSE）图像展示了熔纺带材横截面的微观组织。

MS_Surf图像展示了通过光学显微镜采集的熔纺带材表面形貌。

透射电子显微镜（TEM）图像命名规则如下：
- ms_ribb —— 熔纺带材
- nabh4_ribb —— 经硼氢化钠水溶液清洗后的带材
- liq_ribb —— 苯乙炔加氢反应后回收的带材

phenylacetylene hydrogenation reactions.ods —— 采用新鲜批次催化剂开展苯乙炔加氢反应的反应进程数据，反应混合物的化学组成通过气相色谱法完成定量分析。

X射线光电子能谱（XPS）采集了熔纺态以及苯乙炔加氢反应后回收的熔纺带材表面的谱图。

本研究的材料制备与微观结构分析工作均在波兰科学院冶金与材料科学研究所完成。

材料制备、实验流程、仪器配置、数据采集与结果分析的详细内容已刊载于下述研究：https://doi.org/10.1016/j.susmat.2024.e01055

材料制备：阿米莉亚·热巴（Amelia Zięba）
透射电子显微镜图像采集（使用FEI Tecnai G2、赛默飞世尔ThermoFisher Titan Themis G2 200 Probe Cs校正型电镜）：阿米莉亚·热巴、莉迪亚·利廷斯卡-多布任斯卡
扫描电子显微镜图像采集（使用FEI E-SEM XL-30）：阿米莉亚·热巴
催化性能测试：多罗塔·杜拉钦斯卡
X射线光电子能谱分析：马特乌什·马尔采克

致谢
本研究得到波兰国家科学中心（NCN）项目（项目编号：2021/41/N/ST8/02533）的经费支持。