A Homometallic Tricapped Cubane Cluster: [(Cp*Mo)4B4H4(μ4-BH)3] (Cp* = η5-C5Me5)
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https://figshare.com/articles/dataset/A_Homometallic_Tricapped_Cubane_Cluster_Cp_Mo_sub_4_sub_B_sub_4_sub_H_sub_4_sub_sub_4_sub_BH_sub_3_sub_Cp_sup_5_sup_C_sub_5_sub_Me_sub_5_sub_/2617786
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The reaction of [Cp*MoCl4] with an excess of LiBH4, followed by thermolysis with tellurium powder in toluene, afforded a tricapped cubane cluster, [(Cp*Mo)4B4H4(μ4-BH)3] (1), which represents an unprecedented metal-rich metallaborane cluster with a cubane core containing 58 cluster valence electrons (cve) and three metal–metal bonds.
将[五甲基环戊二烯基四氯化钼(Cp*MoCl4)]与过量硼氢化锂反应，随后在甲苯中与碲粉进行热解，得到三帽立方烷簇合物[(Cp*Mo)4B4H4(μ4-BH)3]（1）。该簇合物为前所未有的富金属金属硼烷簇，其立方烷核心包含58个簇价电子（cve），并存在3条金属-金属键。
创建时间：
2016-02-23
