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Microwave-Assisted Synthesis of Functionalized Shvo-Type Complexes

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Figshare2016-02-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Microwave_Assisted_Synthesis_of_Functionalized_Shvo_Type_Complexes/2284978
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A simple and expeditious microwave-assisted procedure for the synthesis of a variety of Shvo-type ruthenium complexes has been developed by reacting Ru3(CO)12 with variously functionalized tetraarylcyclopentadienones under microwave irradiation in MeOH. Ligand precursors have also been prepared under microwave heating by a bis-aldol condensation of 1,3-diphenylacetone with variously functionalized aromatic diketones. All the reactions were very fast and clean, leading to good yields and purities.
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2016-02-17
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