MATHCAD FIle for simulating cyclic voltammograms of electrochemical-catalytic mechanism

This is original MATHCAD file ready to simulate cyclic voltammograms of an electrochemical-catalytic mechanism in which mass transfer of electrochemically active species is governed by diffusion. The protocol provided in the MATHCAD File of this mechanism enables simulation of cyclic voltammograms as a function of the rate of irreversible catalytic (regenerative) reaction, but also as a function of the rate of electron transfer step. This model is suitable for he beginners in electrochemistry mainly for educational purposes. The MATHCAD File is ready for simulation in MATHCAD 14 or higher versions of MATHCAD, and it is free for use for everyone.

本文件为原始MATHCAD文件，可用于模拟电化学-催化机理（electrochemical-catalytic mechanism）下的循环伏安图（cyclic voltammograms），该体系中电化学活性物种（electrochemically active species）的传质（mass transfer）过程由扩散主导。本文件中提供的该机理模拟方案，可通过调控不可逆催化（再生）反应（irreversible catalytic (regenerative) reaction）速率与电子转移步骤（electron transfer step）速率，实现循环伏安图的模拟。本模型主要面向电化学初学者，适用于教学场景。该MATHCAD文件可在MATHCAD 14及更高版本中直接运行模拟，且面向所有用户免费开放使用。