A Review on Emerging Organic-containing Microporous Material Membranes for Carbon Capture and Separation

<strong>Published article:</strong> Prasetya, N., Himma, N. F., Doddy Sutrisna, P., Wenten, I. G. &amp; Ladewig, B. P. <em>Chem. Eng. J.</em> 123575 (2019). https://doi.org/10.1016/j.cej.2019.123575 <strong>Abstract</strong> Membrane technology has gained great attention as one of the promising strategies for carbon capture and separation. Intended for such application, membrane fabrication from various materials has been attempted. While gas separation membranes based on dense polymeric materials have been long developed, there is a growing interest to use porous materials as the membrane material. This review then focuses on emerging porous materials to be used for the fabrication of membranes that are designed for CO₂separation. Criteria for selecting microporous material are first discussed, including physical and chemical properties, and parameters in membrane fabrication. Membranes based on emerging porous materials,such as metal-organic frameworks, porous organic frameworks, and microporous polymers,are then reviewed. Finally, special attention is given to recent advances, challenges, and perspectives in the development of such membranes for carbon capture and separation.**已发表论文：** Prasetya, N.、Himma, N. F.、Doddy Sutrisna, P.、Wenten, I. G. 与 Ladewig, B. P.，《化学工程期刊（Chem. Eng. J.）》，123575 (2019)。https://doi.org/10.1016/j.cej.2019.123575 **摘要：** 膜技术作为极具前景的碳捕获与分离策略之一，已获得广泛关注。针对此类应用场景，学界已尝试采用多种材料制备气体分离膜。尽管基于致密聚合物材料的气体分离膜已得到长期发展，但以多孔材料作为膜基材的研究正日益受到学界关注。本综述聚焦可用于制备二氧化碳（CO₂）分离膜的新兴多孔材料。本文首先讨论了微孔材料的筛选标准，涵盖其物理化学性质以及膜制备过程中的相关参数。随后，本文对基于新兴多孔材料（包括金属有机框架（metal-organic frameworks）、多孔有机框架（porous organic frameworks）与微孔聚合物）的分离膜进行了综述。最后，本文重点探讨了此类碳捕获与分离膜的最新研究进展、现存挑战及未来发展前景。