Electrochemical Synthesis and Magnetic Properties of [Cu9W6]: The Ultimate Member of the Quindecanuclear Octacyanometallate-Based Transition-Metal Cluster?

[Cu9W6], synthesized by the electrochemical method, may be the ultimate member of the quindecanuclear octacyanometallate-based transition-metal cluster. Its single-crystal structure and magnetic properties were characterized.[Cu9W6]采用电化学法（electrochemical method）合成，或为基于八氰合金属基（octacyanometallate）的十五核过渡金属团簇（transition-metal cluster）的终极成员。该化合物的单晶结构与磁学性质已得到表征。