Organocatalyzed Atroposelective Dynamic Kinetic Resolutions via Transient Seven-Membered Cyclic Hemiacetals

DFT_optimized structures accompanying the study "Beyond Five- and Six-Membered Ring Intermediates: Transient Seven-Membered Cyclic Hemiacetals for Organocatalyzed Atroposelective Dynamic Kinetic Resolutions", where conformers occur, they are always named from the lowest Gibbs energy to the highest in ascending order from c1 (sometimes omitted), c2, c3, ... Note: R-3a.xyz corresponds to R-3c.xyz in the manuscript.经密度泛函理论（DFT）优化的结构，配套于该项研究《超越五元和六元环中间体：用于有机催化阻转选择性动态动力学拆分的瞬态七元环半缩醛》；当存在构象异构体时，所有构象均按照吉布斯自由能由低到高的升序依次命名为c1（部分情况下可省略）、c2、c3…… 注意：手稿中的R-3a.xyz对应R-3c.xyz。