Data for: Epoxidation of alkenes by oxo-vanadium (IV) tetradentate Schiff base complex as an efficient catalyst with tert-butyl hydroperoxide
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2017-04-28
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Can the Disproportion of Oxidation State III Be Favored in Ru II −OH 2 /Ru IV O Systems?
Three new Ru−aqua complexes containing a mixed carbene and pyridylic ligands with general formulas [Ru(CNC)(bpy)(H2O)](PF6)2 (1) (CNC is 2,6-bis(butylimidazol-2-ylidene)pyridine; bpy is 2,2‘-bipyridin
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Investigation of Molybdenum Tetracarbonyl Complexes As Precursors to Mo VI Catalysts for the Epoxidation of Olefins
The one-dimensional organic−inorganic hybrid material [MoO3(bipy)] (3) (bipy = 2,2′-bipyridine) is obtained rapidly and in quantitative yield by the reaction of the complex cis-[Mo(CO)4(bipy)] (1) wit
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Dicarbonyl{[2-(diphenylphosphino)ethyl]cyclopentadienyl} Group VI Metal Hydrides, Halides, and Anions: Precursors for Olefin Epoxidation Catalysts
Oxidative decarbonylation of (η5-C5R5)Mo(CO)3X and isoelectronic four-legged piano-stool Mo(II) precursors to homogeneous olefin epoxidation catalysts has garnered significant attention as an alter
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Cyclopentadienyl Molybdenum(II/VI) N-Heterocyclic Carbene Complexes: Synthesis, Structure, and Reactivity under Oxidative Conditions
A series of N-heterocyclic carbene (NHC) complexes CpMo(CO)2(NHC)X (NHC = IMe = 1,3-dimethylimidazol-2-ylidene, X = Br, 1; NHC = 1,3-dipropylimidazol-2-ylidene, X = Br, 2; NHC = IMes = 1,3-bis(2,4,6-t
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Isomeric Complexes of [Ru II (trpy)(L)Cl] (trpy = 2,2′:6′,2′′-Terpyridine and HL = Quinaldic Acid): Preference of Isomeric Structural Form in Catalytic Chemoselective Epoxidation Process
The present work deals with the isomeric complexes of the molecular composition [RuII(trpy)(L)Cl] in 1 and 2 (trpy = 2,2′:6′,2′′-terpyridine, L = deprotonated form of quinaldic acid, HL). Isomeric ide
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