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Three-Stage Binary Switching of Azoaromatic Polybase

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NIAID Data Ecosystem2026-03-07 收录
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An OFF–ON–OFF-type three-stage binary switching was realized with an azoaniline-based polybase 1. The optical properties of 1 and [1·2H]2+ are essentially indistinguishable to the naked eye but distinctively different from those of [1·H]+ to produce an unusual bell-shaped response as a function of protonation state; the underlying molecular mechanism was unraveled by a combination of experimental and DFT computational studies.

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2012-12-21
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