A Stable Hydrido Amido Ruthenium Complex Bearing a Tridentate Iminophosphorane−Phosphine−Amine Ligand
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A heterotridentate (P,N,N‘) ligand featuring phosphine, iminophosphorane, and amine groups has been prepared in high yield. The corresponding dichlororuthenium(II) complex reacts with base in 2-propanol to give a stable hydrido amido complex. The lack of hydrogens that are α to the amine allowed for the isolation and structural characterization of this hydrido amido species by X-ray diffraction.
创建时间:
2006-01-16



