Re-Mediated C–C Coupling of Pyridines and Imidazoles
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Rhenium tricarbonyl complexes with three N-heterocyclic ligands (N-alkylimidazoles or pyridines) undergo deprotonation with KN(SiMe3)2 and then oxidation with AgOTf to afford complexes with pyridylimidazole or bipyridine bidentate ligands resulting from deprotonation, C–C coupling and rearomatization.
创建时间:
2016-02-20



