Mild Reduction Route to a Redox-Active Silicon Complex: Structure and Properties of (IP<sup>2–</sup>)<sub>2</sub>Si and (IP<sup>–</sup>)<sub>2</sub>Mg(THF) (IP = α-Iminopyridine)
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Use of SiCl4 as an organometallic reagent can be complicated by access to Si3+, Si2+, and unwanted sigmatropic rearrangements. Herein we report a mild reduction route, using (IP–)2Mg(THF) (1) and Mg metal, to cleanly access (IP2–)2Si (2). Electrochemical measurements show that IP2– is stabilized by Si4+ > Al3+ > Mg2+.
创建时间：
2012-05-14
