Synthesis and Reactivity of Platinum Group Metal Complexes Featuring the New Pincer-like Bis(phosphino)silyl Ligand [κ<sup>3</sup>-(2-Ph<sub>2</sub><i>P</i>C<sub>6</sub>H<sub>4</sub>)<sub>2</sub><i>Si</i>Me]<sup>−</sup> ([PSiP]): Application in the Ruthenium-Mediated Transfer Hydrogenation of Keton
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数据链接：
https://figshare.com/articles/dataset/Synthesis_and_Reactivity_of_Platinum_Group_Metal_Complexes_Featuring_the_New_Pincer_like_Bis_phosphino_silyl_Ligand_sup_3_sup_2_Ph_sub_2_sub_i_P_i_C_sub_6_sub_H_sub_4_sub_sub_2_sub_i_Si_i_Me_sup_sup_PSiP_Application_in_the_Ruthenium_Mediated_Transfer_Hydr/2968624数据链接链接失效反馈
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资源简介：
The synthesis of coordinatively unsaturated Ru, Rh, Pd, and Pt complexes supported by the new pincer-like bis(phosphino)silyl ligand [κ3-(2-Ph2PC6H4)2SiMe]− ([PSiP]) is described. In the first application of silyl pincer-type complexes in transfer hydrogenation catalysis, [PSiP]Ru species were shown to be effective in mediating the reduction of ketones employing basic iPrOH as the hydrogen source.
创建时间：
2007-12-17
