Practical, Scalable, High-Throughput Approaches to η<sup>3</sup>-Pyranyl and η<sup>3</sup>-Pyridinyl Organometallic Enantiomeric Scaffolds Using the Achmatowicz Reaction
收藏NIAID Data Ecosystem2026-03-06 收录
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A unified strategy for the high-throughput synthesis of multigram quantities of the η3-oxopyranyl- and η3-oxopyridinylmolybdenum complexes TpMo(CO)2(η3-oxopyranyl) and TpMo(CO)2(η3-oxopyridinyl) is described (Tp = hydridotrispyrazolylborato). The strategy uses the oxa- and aza-Achmatowicz reaction for the preparation of these organometallic enantiomeric scaffolds, in both racemic and high enantiopurity versions.
创建时间：
2016-10-12
