Bi(OTf)3‑Catalyzed Tandem Meyer–Schuster Rearrangement and 1,4-Addition to the Resulting Vinyl Ketone
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Bi(OTf)3-catalyzed Meyer–Schuster rearrangement of electron-rich propargyl alcohols, followed by 1,4-addition of the resulting vinyl ketone, proceeded smoothly though Meyer–Schuster rearrangement of primary propargyl alcohols is rare. This tandem reaction can be extended to an intramolecular version, featuring a one-pot dihydroquinolone synthesis.
创建时间：
2016-02-16
