Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases
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The efficient synthesis of hydrosilanes by catalytic hydrogenolysis of chlorosilanes is described using an iridium (III) pincer catalyst. A careful selection of a nitrogen base (including sterically hindered guanidines and phosphazenes) can unlock the preparation of Me3SiH, Et3SiH, and Me2SiHCl in high yield (up to 98%) directly from their corresponding chlorosilanes.
创建时间：
2021-08-17
