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Copper(I)-Catalyzed Asymmetric Pinacolboryl Addition of <i>N</i>‑Boc-imines Using a Chiral Sulfoxide–Phosphine Ligand

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NIAID Data Ecosystem2026-03-08 收录
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Highly efficient and enantioselective copper­(I)-catalyzed pinacolboryl addition of N-Boc-imines is reported. By using a single chiral sulfoxide-(dialkyl)­phosphine (SOP) ligand, both enantiomeric isomers of α-amino boronic esters were obtained through an achiral counteranion switch.

创建时间:
2016-02-15
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