Palladium-Catalyzed Asymmetric C–H Arylation for the Synthesis of Planar Chiral Benzothiophene-Fused Ferrocenes
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An intramolecular enantioselective C–H arylation of ferrocenyl aryl sulfides was performed with a palladium catalyst. Planar chiral thiophene compounds with a ferrocene skeleton were constructed in good enantioselectivities (up to 99% ee) and high yields, and the utility of the obtained chiral sulfides as ligands in catalytic reactions has been demonstrated.
创建时间：
2018-11-14
