Intramolecular Direct C–H Arylation via a Metallocenic Radical Pathway: Stereospecific Approach to Planar-Chiral Ferrocenes
收藏NIAID Data Ecosystem2026-03-10 收录
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Transition metal-free synthesis of planar-chiral 1,2-fused ferrocenes via intramolecular direct C–H bond arylation was achieved. The C–H arylation reactions promoted by a catalytic amount of 1,10-phenanthroline highlighted a unique planar-chiral metallocenic radical intermediate, generated from iodoferrocenes via a single-electron transfer process.
创建时间：
2017-10-05
