Gold(I)-Catalyzed Enantioselective Polycyclization Reactions

NIAID Data Ecosystem2026-03-06 收录

金催化反应

立体选择性合成

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Gold(I)-Catalyzed Enantioselective Polycyclization Reactions

创建时间：

2010-06-23

New Insights into the Torquoselectivity of the Staudinger Reaction

有机反应机理

立体选择性合成

To understand the torquoselectivity and the electronic effects of the Staudinger reaction, a study using a combination of experiments and DFT calculations has been conducted for the reactions of an un

NIAID Data Ecosystem60

Brønsted Acid-Catalyzed Diastereoselective Synthesis of Spiroisoindolinones from Enamides

立体选择性合成

螺环异吲哚啉酮合成

A highly diastereoselective synthesis of spiroisoindolinones from enamides and 3-hydroxy-isoindolinones is reported. The reaction proceeds rapidly in the presence of p-toluenesulfonic acid as a Brønst

NIAID Data Ecosystem60

Highly Enantioselective Synthesis of Chiral Allenes by Sequential Creation of Stereogenic Center and Chirality Transfer in a Single Pot Operation

手性化合物合成

立体选择性合成

Chiral allenes are readily accessed in a single pot operation in the reaction of terminal alkynes, aldehydes, chiral secondary amines, and zinc halides in good yields (up to 77% yield) and excellent e

NIAID Data Ecosystem40

Synthesis of Fused Carbocycles via a Selective 6- Endo Dig Gold(I)-Catalyzed Carbocyclization

金催化反应

环状碳酸酯合成

A gold-catalyzed synthesis of fused carbocycles via a regioselective 6-endo dig process is reported. The selectivity can be modulated by the steric and electronic properties of gold(I) complexes. The

NIAID Data Ecosystem60

Diastereoselective Synthesis of γ- and δ‑Lactams from Imines and Sulfone-Substituted Anhydrides

立体选择性合成

内酰胺杂环合成

Sulfone-substituted γ- and δ-lactams have been prepared in a single step with high diastereoselectivity. Sulfonylglutaric anhydrides produce intermediates that readily decarboxylate to provide δ-lacta

NIAID Data Ecosystem40

Gold(I)-Catalyzed Enantioselective Polycyclization Reactions

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