Ni(II)−Bis[(<i>R</i>,<i>R</i>)-<i>N</i>,<i>N</i>‘-dibenzylcyclohexane-1,2-diamine]Br<sub>2</sub> Catalyzed Enantioselective Michael Additions of 1,3-Dicarbonyl Compounds to Conjugated Nitroalkenes
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A highly enantioselective Michael addition of 1,3-dicarbonyl compounds to nitroalkenes has been developed that employs a newly developed Ni(II)−(bis)diamine based catalyst. The reaction scope includes substituted and unsubstituted malonates, β-ketoesters, and nitroalkenes bearing aromatic and aliphatic residues. Ease of synthesis of this complex is noteworthy.
创建时间：
2016-05-05
