Coordination of Phosphinoboranes R<sub>2</sub>PB(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub> to Platinum: An Alkene-Type Behavior
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The paucity of boron-containing heteroalkene complexes prompted us to explore the coordination of phosphinoboranes. The complexes {[R2PB(C6F5)2]Pt(PPh3)2} (R = Cy, t-Bu) were obtained by ethylene displacement. Spectroscopic and crystallographic data indicated symmetric side-on coordination of the phosphinoborane to Pt. Thorough analysis of the bonding situation by computational means revealed important similarities but also significant differences between the phosphinoborane and ethylene complexes.
创建时间：
2012-04-18
