Copper-Catalyzed β‑Trifluoromethylation of Conjugated Hydrazones
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The Cu-catalyzed direct β-trifluoromethylation of α,β-unsaturated aldehyde N,N-dibenzylhydrazones with Togni hypervalent iodine reagent is described. The reaction yields stereodefined CF3-alkenyl derivatives under mild conditions and is proposed to proceed via a radical process.
创建时间：
2014-09-19
