Sequential Allenylidene/Vinylidene Cyclization for Stereoselective Construction of Bicyclic Carbocycles from Propargyl Alcohol
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Consecutive cyclization reactions of phenyl propargyl alcohols 1 and 2 are catalyzed by [Ru]NCCH3+ ([Ru] = Cp(PPh3)2Ru) in cosolvent CHCl3/MeOH at 60 °C, to afford the fused cyclic compounds 11a (R = Me) and 10a (R = Me), respectively.
创建时间：
2016-02-20
