Enantioselective Epoxidation of β,γ-Unsaturated Carboxylic Acids by a Cooperative Binuclear Titanium Complex
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Enantioselective epoxidation of β,γ-unsaturated carboxylic acids with a cooperative binuclear titanium complex has been developed to provide single diastereomer γ-lactones in high yields and enantioselectivities via intramolecular cyclization. For the success of the reaction, the proper distance between the carboxylic acid and alkene is quite important, offering the regioselective epoxidation of unsaturated carboxylic acids bearing two similar alkenes.
创建时间：
2019-03-18
