Easy Access to Allylic Sulfones Through Transition-Metal-Free Hydrosulfonylation Of Allenes
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A Brønsted acid-mediated addition of (hetero)aryl and (cyclo)alkyl sodium sulfinates to N-allenyl derivatives, which proceeds in water, is described under very smooth conditions. This reaction provided a practical and efficient protocol for the regio- and stereoselective synthesis of allylic sulfones in an atom- and step-economic fashion.
创建时间：
2021-10-18
