Regioselective Functionalization of Enamides at the α‑Carbon via Unsymmetrical 2‑Amidoallyl Cations
收藏NIAID Data Ecosystem2026-03-10 收录
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A new method to functionalize enamides via an intermediacy of unsymmetrical 2-amidoallyl cations is reported. Generated under mild Brønsted acid catalysis, these reactive species were found to undergo addition with various nucleophiles at the less substituted α-carbon to produce highly substituted enamides in high yields with complete control of regioselectivity.
创建时间：
2017-04-26
