Polymerization of Aryl Isocyanides Possessing Bulky Substituents at an <i>o</i><i>rtho </i>Position Initiated by Organorhodium Complexes
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
The organorhodium(I) complexes Rh(R)(nbd)(PPh3) (R = Me2C6H3, 2,4,6-Pri3C6H2, 2-PhC6H4; nbd = 2,5-norbornadiene), prepared from the reaction of [Rh(nbd)Cl]2 with PPh3 and LiR, effectively initiate the polymerization of aryl isocyanides possessing bulky substituents at an ortho position in the presence of PPh3 to provide polyisocyanides in good yields.
创建时间：
2016-08-26
