An Unprecedented Dinuclear Alkylrhodium(III) Complex Built up by Two 14-Electron [RhCl<sub>2</sub>(alkyl)(PR<sub>3</sub>)] Units
收藏NIAID Data Ecosystem2026-03-06 收录
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Reaction of HCl with [RhCl(C2H4)(PR3)]2 affords the dinuclear alkylrhodium(III) complex [RhCl2(C2H5)(PR3)]2, the structure of which has been determined crystallographically. PR3 is the formerly unknown trialkyl phosphine tBu2PCH2CH2C6H3-2,6-Me2, prepared in three steps from tBuPCl2. Treatment of the title compound with CO gives the mononuclear rhodium dicarbonyl cis-[RhCl(CO)2(PR3)], being the first fully characterized complex of this type.
创建时间：
2016-08-18
