Generation of α‑Imino Gold Carbenes through Gold-Catalyzed Intermolecular Reaction of Azides with Ynamides
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资源简介：
The generation of α-imino gold carbenes via gold-catalyzed intermolecular reaction of azides and ynamides is disclosed. This new methodology allows for highly regioselective access to valuable 2-aminoindoles and 3-amino-β-carbolines in generally good to excellent yields. A mechanistic rationale for this tandem reaction, especially for the observed high regioselectivity, is supported by DFT calculations.
创建时间：
2016-02-15
