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A Short Biomimetic Synthesis of the Meroterpenoids Guajadial and Psidial A

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NIAID Data Ecosystem2026-03-06 收录
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The biosynthesis of the meroterpenoid guajadial was previously hypothesized to occur via a hetero-Diels−Alder reaction between caryophyllene and an o-quinone methide. This hypothesis has been verified via the biomimetic synthesis of guajadial and psidial A in an aqueous three-component coupling reaction, between caryophyllene, benzaldehyde, and diformylphloroglucinol.

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2016-02-25
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