Formation of Multinary Intermetallics from Reduction of Perovskites by Aluminum Flux: M<sub>3</sub>Au<sub>6+</sub><i><sub>x</sub></i>Al<sub>26</sub>Ti (M = Ca, Sr, Yb), a Stuffed Variant of the BaHg<sub>11</sub> Type
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New intermetallic phases were synthesized by reacting oxidic perovskites and gold metal in aluminum flux. The combination of MTiO3 (M = Ca, Sr, Ba) and Au metal in excess molten aluminum produces quaternary compounds M3Au6+xAl26Ti with a stuffed BaHg11 structure type. An analogue with M = Yb was also synthesized; it shows mixed valent behavior.
创建时间：
2004-01-12
