Proton-Induced Dynamic Equilibrium between Cyclometalated Ruthenium rNHC (Remote N-Heterocyclic Carbene) Tautomers with an NAD+/NADH Function
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Cyclometalated ruthenium(II) complexes having acridine moieties have been synthesized and characterized by spectroscopic methods. Protonation of the acridine nitrogen of the ruthenium(II) complexes not only causes dynamic equilibrium with remote N-heterocyclic carbene RuC complexes but also generates the NAD+/NADH redox function driven by a proton-coupled two-electron transfer accompanying a reversible C–H bond formation in the pyridinium ring.
创建时间：
2016-02-23
