An Unsymmetric Oxo/Imido-Bridged Germanium-Centered Singlet Diradicaloid

NIAID Data Ecosystem2026-03-06 收录

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资源简介：

An Unsymmetric Oxo/Imido-Bridged Germanium-Centered Singlet Diradicaloid

创建时间：

2016-02-25

A Useful Access to the Chemistry of the Indenyl-Osmium-Triisopropylphosphine Moiety

有机金属化学

配位化学

Complex OsH3Cl(PiPr3)2 (1) reacts with indenyllithium to give OsH(η5-C9H7)(PiPr3)2 (2), which affords (3) by treatment with methyl trifluoromethanesulfonate. In acetonitrile, complex 3 evolves to an

NIAID Data Ecosystem40

Seven-Membered Cyclic Dialkylstannylene and -Plumbylene Compounds Stabilized by Agostic-type B−H···E Interactions [E = Sn, Pb]

有机金属化学

化合物稳定性

The reaction between [[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]Li(THF)3]2 and either Cp2Sn or Cp2Pb in toluene cleanly gives the compounds rac-[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]2E in moderate yield [E = Sn

NIAID Data Ecosystem20

Regiodiscriminating Reactivity of Isolable NHC-Coordinated Disilenyl Germylene and Its Cyclic Isomer

有机金属化学

物理有机化学

An isolable NHC-coordinated disilenyl germylene R2SiSiR-GePh·NHCiPr2Me2 (5b: R = 2,4,6-triisopropylphenyl, NHCiPr2Me2 = 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene) is obtained from the reaction o

NIAID Data Ecosystem20

TiNR vs Ti−R′ Functional Group Selectivity in Titanium Imido Alkyl Cations from an Experimental Perspective

有机金属化学

催化反应机理

A study of the reactions of the titanium imido methyl cation [Ti(NtBu)(Me3[9]aneN3)X]+ (5+, X = Me) and key analogues (6+, X = CH2SiMe3; 7+, X = Cl) with a range of unsaturated substrates provides a c

NIAID Data Ecosystem30

Facile Carbon–Carbon Bond Formation and Multiple Carbon–Hydrogen Bond Activations Promoted by Methylene-Bridged Iridium/Ruthenium Complexes

有机金属化学

双金属配合物

The methylene-bridged complex [IrRu(CO)4(μ-CH2)(dppm)2][BF4] (1; dppm = μ-Ph2PCH2PPh2) reacts with 1,1-dimethylallene and 1,2-butadiene, resulting in coupling of the cumulene and the bridging methylen

NIAID Data Ecosystem20

An Unsymmetric Oxo/Imido-Bridged Germanium-Centered Singlet Diradicaloid

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