A Highly Efficient Luminescent Pt<sub>2</sub>Tl<sub>2</sub> Chain with a Short Tl<sup>I</sup>–Tl<sup>I</sup> Interaction
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资源简介：
The preparation of an unsupported tetranuclear cluster with a linear Pt0–TlI–TlI–Pt0 metal chain is described. The complex shows strong red emission in the solid state, having a quantum yield of 73%. Density functional theory (DFT) and time-dependent DFT calculations show that red emission originated from a platinum to thallium–thallium charge-transfer excited state.
创建时间：
2016-02-18
