Diastereo- and Enantioselective Aza-MBH-Type Reaction of Nitroalkenes to <i>N</i>-Tosylimines Catalyzed by Bifunctional Organocatalysts
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资源简介：
The first example of diastereo- and enantioselective aza-MBH-type reaction was accomplished by the asymmetric synthesis of β-nitro-γ-enamines via a (1R,2R)-diaminocyclohexane thiourea derivative mediated tandem Michael addition and aza-Henry reaction in good yields (up to 95%) and high enantioselectivities (up to 91% ee) and diastereoselectivities (up to 1:99 dr).
创建时间：
2009-08-06
