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Synthesis of Enantiopure P‑Stereogenic Diphosphacrowns using P‑Stereogenic Secondary Phosphines

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NIAID Data Ecosystem2026-03-09 收录
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A new synthetic route to enantiopure P-stereogenic benzodiphosphacrowns using a P-stereogenic secondary bisphosphine as the key building block is reported. Syntheses of the enantiomer and P-stereogenic crowns with various ring structures, as well as deboranation of the crown compounds and subsequent reaction with a platinum complex, are described.

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2016-02-19
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